[Homura has definitely noticed Hijikata. It's hard not to when the wind carries a scent of tobacco. She has been in her magical form this whole time, which is good since she can act more easily.
She makes sure to use time stop to make a sound on the far end of the street, to distract Hijikata long enough. While he is distracted, Homura puts the gun and everything she purchased into her hammerspace shield, like they never were in her possession. Instead she takes a package of something else out that looks almost exactly same as the gun case she had (she was prepared for trouble beforehand).
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She makes sure to use time stop to make a sound on the far end of the street, to distract Hijikata long enough. While he is distracted, Homura puts the gun and everything she purchased into her hammerspace shield, like they never were in her possession. Instead she takes a package of something else out that looks almost exactly same as the gun case she had (she was prepared for trouble beforehand).
She continues to walk like nothing happened.]